LAPILLY TUFF
Category: Pyroclastic
Type Ignimbrite
Commons Lapilli tuff is a consolidated pyroclastic rock containing more than 75% lapilli. Lapilli are pyroclasts ranging from 2 to 64 mm in size, formed by the fragmentation of surrounding material during a volcanic eruption. They may consist of individual crystals, crystal aggregates, volcanic glass, or rock fragments. The finest-grained pyroclasts are ash grains, with particle sizes smaller than 2 mm. In addition to ash, tuff may contain coarser pyroclastic material, such as volcanic bombs—rounded pyroclasts larger than 64 mm with a "bread-crust" surface, which were partially or completely molten during formation and transport—and blocks—angular pyroclasts larger than 64 mm that were solid at the time of formation. Lapilli tuff can form through the fallout of pyroclasts during an eruption or through deposition from pyroclastic flows. Ignimbrite is the genetic term for deposits resulting from ash-pumice pyroclastic flows. Depending on the temperature at the time of deposition, ignimbrites can be classified as welded or non-welded. Welded ignimbrites are characterized by the presence of flattened “fiamme”- typically deformed pumice fragments that underwent plastic deformation due to heat and the weight of overlying pyroclastic material. The lapilli tuff from Ipolytarnóc is part of the massive tuff complexes found in the Pannonian Basin region. It originates from a 10–40 m thick stratified sequence of ignimbrites, referred to in older literature as the Gyulakeszi Rhyolite Tuff Formation or the "Lower Rhyolite Tuff" (Lukács et al., 2018; Pálfy et al., 2007). According to the latest lithostratigraphic classification, the Gyulakeszi Rhyolite Formation was renamed to Tihamér Rhyolite Lapilli Tuff Formation (Lukács et al., 2022). Its spatial extent reaches into Slovakia, where lapilli tuffs occur within the Bukovina Formation (Vass et al., 2002). The best-known localities are Mučín and Lipovany, which were dated by Šarinová et al. (2021). The ignimbrites at the Ipolytarnóc site are products of explosive silicic volcanism dating to the Miocene (17.4–17.2 Ma) (Karátson et al., 2022; Pálfy et al., 2007; Lukács et al., 2018). They overlie sandstones in which fossilized tracks of vertebrates and birds were discovered in 1900. The site is renowned for these paleontological finds, which were preserved on an ancient riverbank thanks to a volcanic eruption that instantly blanketed the sand with a thick layer of ignimbrite. A total of 3,000 fossil tracks representing 11 animal species have been documented there (Kordos, 1985). The lapilli tuffs originated from the Eger volcanic center in present-day Hungary; this eruption generated multiple pyroclastic flows, at least three of which reached the Ipolytarnóc area. Classified as a Plinian eruption with a Volcanic Explosivity Index (VEI) greater than 7 (on a scale where the maximum is 8), the event at the Eger volcanic center resembled the eruption of Vesuvius in 79 AD (Karátson et al., 2022). However, the Vesuvius eruption had a slightly lower VEI, in the range of 5–6. The temperature of a pyroclastic flow decreases during transport; in Pompeii and Herculaneum, located near Vesuvius, many people perished beneath hot pyroclastic flows. The Eger volcanic center, considered the source of the material found at Ipolytarnóc, is currently located 75 km away from the site. By the time the pyroclastic flows reached present-day Ipolytarnóc, they had already cooled. Consequently, intact, uncharred tree trunks and branches, leaves (Hably, 1985), and animal tracks (Kordos, 1985) have been preserved at the site. It is estimated that the eruption covered an area of 1,650 km² and produced a total ignimbrite volume of 99 km³, corresponding to 58 km³ of magma (Karátson et al., 2022). Recent historical eruptions with a VEI of 7 include the Taupo eruption in New Zealand in 232 AD (30 km³ of magma) and the Late Bronze Age Minoan eruption of Santorini (82 km³ of magma). Today, Ipolytarnóc is rightly regarded as an "ancient Pompeii"; it is a protected natural area and part of the Novohrad-Gemer Geopark.
Name origin The name "tuff" originates from the Italian word tufo and the French word tuf. The term tuff was first defined by Phillips in 1818 (Phillips, 1815). The word "lapilli" derives from the Latin “lapillus”, meaning "small stone" (Lyell, 1835). The term "ignimbrite" was coined by Marshall (1932) and is a compound of two Latin words: “ignis” (fire) and” imber (shower).
Locality Ipeľský Trnovec (Hungarian Ipolytarnóc), Novohrad County, Hungary (sample from the V. Konečný archive)
GPS: 48° 14' 12" N, 19° 39' 25" E
Major minerals The pyroclasts consist of glass fragments (pumice and glass shards), minerals -crystaloclasts (quartz, plagioclase - An30–50, biotite) and rock fragments - lithoclasts of both volcanic origin (vitrophyric lithoclasts and recrystallized glass) and non-volcanic origin (siltstones, mudstones, and claystones). The pyroclasts are cemented by fine volcanic ash composed of glass fragments, which are often altered to clay minerals.
Accessory minerals Apatite, zircon, allanite, ilmenite.
Classification Classification of lapilli tuff is based on modal composition within the polymodal classification scheme for pyroclastic rocks defined by the content of blocks/bombs, lapilli, and ash (Fisher, 1966). Lapilli tuff from Ipolytarnóc is plotting into the field characterized by an ash and lapilli content less than 75 vol. % and a block/bomb content less than 25 vol. %. Giordano & Cas (2021) published a new classification of ignimbrites based on the volume of ash-pumice flow material and their areal extent in the field.
Colour Light gray with white pumice fragments.
Structure Massive.
Granularity Coarse-grained rock (3 mm – 1 cm).
Texture Pyroclastic, crystallo-vitroclastic.
Alterations Bentonitization – the breakdown of glass and biotite into clay minerals of the smectite group.
Petrographic characteristics White pumice fragments larger than 2 mm form lapilli-sized clasts "floating" in a tuffaceous matrix. The relative proportions of lapilli-sized clasts and tuff matrix justify the classification as lapilli tuff. The massive, poorly sorted structure indicates transport within dense pyroclastic flows (laminar flow). Deposition from pyroclastic flows is further evidenced by fragments of charred plant matter scattered throughout the tuff (incorporated during transport).
Usage It is used as a decorative stone. It is processed into aggregate for road construction and other building works. Stratified ignimbrites that split easily are used to produce tiles for building interiors and gardens. An unconventional application of ignimbrites is the Yucca Mountain radioactive waste repository, constructed within ignimbrite deposits in Nevada, USA.
Literature Fisher, R.V. 1966: Rocks composed of volcanic fragments and their classification. Giordano, G., Cas, R., 2021: Classification of ignimbrites and their eruptions. Earth-Science Reviews, 220, 103697. Hably, L., 1985: Early Miocene plant fossils from Ipolytarnóc, N. Hungary. Geologica Hungarica series, Palaeontologica, 45, 78-255. Karátson, D., Biró, T., Portnyagin, M., Kiss, B., Paquette J.-L., Cseri, Z., Hencz, M., Németh, K., Lahitte, P., Márton, E., Kordos, L., Józsa, S., Hably, L., Müller, S., Szarvas, I., 2022: Large-magnitude (VEI ≥ 7) ‘wet’ explosive silicic eruption preserved a Lower Miocene habitat at the Ipolytarnóc Fossil Site, North Hungary. Nature, Scientific Reports, 12, 9743 (2022). https://doi.org/10.1038/s41598-022-13586-3 Kordos, L., 1985: Footprints in Lower Miocene sandstone at Ipolytarnóc, N Hungary (in Hungarian with English resume), Geol. Hung., Ser. Palaeontol., 46, 257–415. Lukács, R., Harangi, Sz., Gál., P., Szepesi, J., Di Capua, A., Norini G., Sulpizio, R., Groppellini, G., Fodor, L., 2022: Formal definition and description of lithostratigraphic units related to the Miocene silicic pyroclastic rocks outcropping in the Northern Hungary: A revision. Geologica Carpathica, 73, 2, 137-158. Lukács, R., Harangi, Sz., Guillong, M., Bachmann, O., Fodor, L., Buret, Y., Dunkl, I., Sliwinski, J., von Quadt, A., Peytcheva, I., Zimmerer, M., 2018: Early to Mid-Miocene syn extensional massive silicic volcanism in the Pannonian Basin (East- Central Europe): Eruption chronology, correlation potential and geodynamic implications. Earth-Science Reviews, 179, 1-19. Lyell, C., 1835: Principles of Geology. Murray, London, 4th Edition, Vol. 1, 406 pp. Marshall, P., 1932: Notes on some volcanic rocks of the North Island of New Zealand. New Zealand Journal of Science and Technology, 13, 198-200. Pálfy, J., Mundil, R., Renne, P.R., Bernor, R.L., Kordos, L., Gasparik, M., 2007: U–Pb and 40Ar/39Ar dating of the Miocene fossil track site at Ipolytarnóc (Hungary) and its implications. Earth and Planetary Science Letters, 258, 160-174. Phillips, W. 1815: An Outline of Mineralogy and Geology, intended for the use of those who may desire to become acquainted with the elements of those sciences; especially of young persons. Phillips, London, 193 pp. Šarinová, K., Rybár, S., Jourdan, F., Frew, A., Mayers, C., Kováčová, M., Lichtman, B., Nováková, P., Kováč, M., 2021: 40Ar/39Ar geochronology of Burdigalian paleobotanical localities in the central Paratethys (South Slovakia). Geologica Acta, 19.5, 1-19, I-IV. Vass, D., 2002: Lithostratigraphy of Western Carpathians: Neogene and Buda Paleogene. Bratislava, State Geological Institute of Dionýz Štúr, 1-200 pp (in Slovak with English summary). Vass, D., Túnyi, I., Márton, E., 2006: The Fehér hegy Formation: Felsitic ignimbrites and tuffs at Ipolytarnóc (Hungary), their age and position in Lower Miocene of Northern Hungary and Southern Slovakia. Slovak Geological Magazine, 12, 2, 139-145. Earth-Science Reviews, 1, 287-298.
Photomicrographs
Lapilli tuff consists of crystal fragments, volcanic glass shards, and pumice fragments set in a matrix of volcanic ash. The crystal fragments comprise biotite (Bt), quartz (Qz), and plagioclase (Pl). Under plane-polarized light, the biotite appears greenish-brown and shows signs of alteration. A characteristic feature of the ignimbrite is the presence of deformed pumice fragments; under plane-polarized light, these appear transparent and contain numerous vesicles formed by the escape of volcanic gases, whereas under crossed polars, they appear black and isotropic. The volcanic ash filling the intergranular spaces between the glass, pumice, and crystal fragments appears brown under plane-polarized light, a result of alteration leading to the formation of clay minerals. The width of all photomicrographs is 2.2 mm.
Normative composition
The lapilli tuff is a quartz – q normative rock. Based on the A/CNK (Al2O3/(CaO+Na2O+K2O)) and A/NK (Al2O3/(Na2O+K2O)) molecular ratios, it is a peraluminous rock. This is also reflected in the normative composition, where normative corundum – c is present.
Normative minerals
SiO2
TiO2
ZrO2
Al2O3
Fe2O3
FeO
MnO
MgO
CaO
Na2O
K2O
P2O5
F
S
CO2
Total
Molar proportion of normative mineral
Molecular mass of normative mineral
Weight % of normative mineral
Oxide
(wt. %)
69.88
0.32
16.88
3.69
0.05
1.73
2.73
2.13
2.51
0.09
100.00
Molecular
weight
60.08
79.88
101.96
71.85
70.94
40.31
56.08
61.98
94.20
141.95
Molecular
proportion
1.1631
0.0039
0.1655
0.0520
0.0006
0.0430
0.0488
0.0343
0.0266
0.0006
ap
0.0021
0.0006
0.0021
328.68
0.21
il
0.0039
0.0039
0.0039
151.75
0.60
or
0.1598
0.0266
0.0266
0.0266
556.67
14.83
ab
0.2059
0.0343
0.0343
0.0343
524.46
18.00
an
0.0933
0.0466
0.0466
0.0466
278.21
12.98
c
0.0579
0.0579
101.96
5.91
zvyšky
0.0481
0.0430
0.0000
hy
0.0910
0.0481
0.0430
0.0910
117.04
10.66
q
0.6130
0.6130
60.08
36.83
D: -0.6130
Mg/(Mg+Fe2+): 0.472
Total of normative wt. % 100.00
Comment All Fe is expressed as FeO, therefore, normative magnetite – mt was not formed. Normative anorthite – an was formed from the remaining Ca after the formation of normative orthoclase – or and normative albite – ab. Excess Al was assigned to normative corundum – c following the formation of normative orthoclase, albite, and anorthite. No Ca remained for the formation of normative diopside – di. All Mg and the remaining Fe2+ after the formation of normative ilmenite – il were assigned to normative hypersthene – hy. The normative composition was calculated from the whole-rock chemical analysis of the Ipoly sample (Šarinová et al., 2021), recalculated to an anhydrous basis due to the very high LOI content (10.60 wt. %).
Chemical composition
Based on its whole-rock chemical composition (SiO2, K2O, and Na2O content), the lapilli tuff plots as dacite on the TAS diagram. The glass within the lapilli tuff is rhyolitic in composition, characterized by high SiO2 (>72 wt.%) and K2O (>4 wt.%) contents. Trace element concentrations in the glass—specifically Nb (9.9 ppm), Th (20.7 ppm), and Y (14.5 ppm) (Huraiová, unpublished data)—correlate well with the geochemistry of tuffs in the Eger area (Karátson et al., 2022), confirming that the volcanism originated from the Eger volcanic center located in present-day Hungary. In addition to glass geochemistry, trace elements in zircon—a common accessory mineral in these lapilli tuffs—are also used for correlation purposes.
Ipolytarnóc, Hungary - sample Ipoly, lapilly tuff
SiO2
62.10TiO2
0.28Al2O3
15.00Fe2O3
3.64FeO
n.a.MnO
0.04MgO
1.54CaO
2.43Na2O
1.89K2O
2.23P2O5
0.08LOI
10.60Total
99.84Mg(Mg/Fe2+)
0.46A/CNK
1.51A/NK
2.72
Šarinová et al. 2021
Mučín, Slovakia - fine-grained lapilly tuff
SiO2
62.45TiO2
0.14Al2O3
14.17Fe2O3
3.50FeO
n.a.MnO
0.03MgO
1.27CaO
1.49Na2O
1.21K2O
2.61P2O5
0.02LOI
13.00Total
99.89Mg(Mg/Fe2+)
0.42A/CNK
1.88A/NK
2.94
Šarinová et al. 2021


